The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air
Open accessAbstract
Conventional SO 2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO 2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure–property relationships, have been rarely explored. Here we report the selective removal and sensing of SO 2 using recently unveiled fluorinated metal–organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO 2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO 2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO 2 at low concentrations ranging from 25 to 500 p.p.m.
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Sheldrick, G. M. (2015) · Acta Crystallographica Section C Structural Chemistry · doi:10.1107/s2053229614024218 · Cited by 43,982
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Metal–Organic Frameworks against Toxic Chemicals
Islamoglu, T., Chen, Z., Wasson, M. C., Buru, C. T., Kirlikovali, K. O., Afrin, U., Mian, M. R., & Farha, O. K. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00828 · Cited by 707
Isoreticular chemistry within metal–organic frameworks for gas storage and separation
Fan, W., Zhang, X., Kang, Z., Liu, X., & Sun, D. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213968 · Cited by 584
A reticular chemistry guide for the design of periodic solids
Jiang, H., Alezi, D., & Eddaoudi, M. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00287-y · Cited by 432
Self-citationYounas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Metadata
- Authors
- Tchalala, M. R., Bhatt, P. M., Chappanda, K. N., Tavares, S. R., Adil, K., Belmabkhout, Y., Shkurenko, A., Cadiau, A., Heymans, N., De Weireld, G., Maurin, G., Salama, K. N., & Eddaoudi, M.
- Venue
- Nature Communications
- Published
- 2019-03-22
- Volume
- 10
- Issue
- 1
- Pages
- 1328-1328
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2925261887
- Cited by
- 415
- References
- 3
- FWCI
- 19.81
- Type
- journal article
- Language
- en
- Open access
- gold
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- Tchalala, M. R., Bhatt, P. M., Chappanda, K. N., Tavares, S. R., Adil, K., Belmabkhout, Y., Shkurenko, A., Cadiau, A., Heymans, N., De Weireld, G., Maurin, G., Salama, K. N., & Eddaoudi, M. (2019). Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air. Nature Communications. https://doi.org/10.1038/s41467-019-09157-2
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