The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.
Mechanistic insight into the active centers of single/dual-atom Ni/Fe-based oxygen electrocatalysts
Open accessAbstract
Single-atom catalysts with maximum metal utilization efficiency show great potential for sustainable catalytic applications and fundamental mechanistic studies. We here provide a convenient molecular tailoring strategy based on graphitic carbon nitride as support for the rational design of single-site and dual-site single-atom catalysts. Catalysts with single Fe sites exhibit impressive oxygen reduction reaction activity with a half-wave potential of 0.89 V vs. RHE. We find that the single Ni sites are favorable to promote the key structural reconstruction into bridging Ni-O-Fe bonds in dual-site NiFe SAC. Meanwhile, the newly formed Ni-O-Fe bonds create spin channels for electron transfer, resulting in a significant improvement of the oxygen evolution reaction activity with an overpotential of 270 mV at 10 mA cm−2. We further reveal that the water oxidation reaction follows a dual-site pathway through the deprotonation of *OH at both Ni and Fe sites, leading to the formation of bridging O 2 atop the Ni-O-Fe sites.
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Cites
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From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis
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Cited by
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
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Long‐Range Interactions in Diatomic Catalysts Boosting Electrocatalysis
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Metadata
- Authors
- Wan, W., Zhao, Y., Wei, S., Triana, C. A., Li, J., Arcifa, A., Allen, C. S., Cao, R., & Patzke, G. R.
- Venue
- Nature Communications
- Published
- 2021-09-22
- Volume
- 12
- Issue
- 1
- Pages
- 5589-5589
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3200870191
- Cited by
- 432
- References
- 64
- FWCI
- 11.94
- Type
- journal article
- Language
- en
- Open access
- gold
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- Wan, W., Zhao, Y., Wei, S., Triana, C. A., Li, J., Arcifa, A., Allen, C. S., Cao, R., & Patzke, G. R. (2021). Mechanistic insight into the active centers of single/dual-atom Ni/Fe-based oxygen electrocatalysts. Nature Communications. https://doi.org/10.1038/s41467-021-25811-0
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