The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Electrochemical oxygen reduction to hydrogen peroxide at practical rates in strong acidic media
Open accessAbstract
Electrochemical oxygen reduction to hydrogen peroxide (H 2 O 2) in acidic media, especially in proton exchange membrane (PEM) electrode assembly reactors, suffers from low selectivity and the lack of low-cost catalysts. Here we present a cation-regulated interfacial engineering approach to promote the H 2 O 2 selectivity (over 80%) under industrial-relevant generation rates (over 400 mA cm−2) in strong acidic media using just carbon black catalyst and a small number of alkali metal cations, representing a 25-fold improvement compared to that without cation additives. Our density functional theory simulation suggests a “shielding effect” of alkali metal cations which squeeze away the catalyst/electrolyte interfacial protons and thus prevent further reduction of generated H 2 O 2 to water. A double-PEM solid electrolyte reactor was further developed to realize a continuous, selective (∼90%) and stable (over 500 hours) generation of H 2 O 2 via implementing this cation effect for practical applications.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Grimme, S., Antony, J., Ehrlich, S., & Krieg, H. (2010) · The Journal of Chemical Physics · doi:10.1063/1.3382344 · Cited by 59,686
Ab initio molecular dynamics for liquid metals
Kresse, G., & Hafner, J. (1993) · Physical Review B · doi:10.1103/physrevb.47.558 · Cited by 45,727
Canonical dynamics: Equilibrium phase-space distributions
Hoover, W. G. (1985) · Physical Review A · doi:10.1103/physreva.31.1695 · Cited by 23,465
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process
Campos‐Martin, J. M., Blanco‐Brieva, G., & Fierro, J. L. G. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503779 · Cited by 3,238
High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials
Lu, Z., Chen, G., Siahrostami, S., Chen, Z., Liu, K., Xie, J., Liao, L., Wu, T., Lin, D., Liu, Y., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0017-x · Cited by 1,807
Self-citationEnabling direct H2O2 production through rational electrocatalyst design
Siahrostami, S., Verdaguer-Casadevall, A., Karamad, M., Deiana, D., Malacrida, P., Wickman, B., Escudero-Escribano, M., Paoli, E. A., Frydendal, R., Hansen, T. W., et al. (2013) · Nature Materials · doi:10.1038/nmat3795 · Cited by 1,597
Implicit self-consistent electrolyte model in plane-wave density-functional theory
Mathew, K., Kolluru, V. S. C., Mula, S., Steinmann, S. N., & Hennig, R. G. (2019) · The Journal of Chemical Physics · doi:10.1063/1.5132354 · Cited by 1,418
CO 2 electrolysis to multicarbon products in strong acid
Huang, J. E., Li, F., Ozden, A., Sedighian Rasouli, A., García de Arquer, F. P., Liu, S., Zhang, S., Luo, M., Wang, X., Lum, Y., et al. (2021) · Science · doi:10.1126/science.abg6582 · Cited by 1,359
Cited by
Deng, F., Olvera-Vargas, H., Zhou, M., Qiu, S., Sirés, I., & Brillas, E. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00684 · Cited by 409
Metadata
- Authors
- Zhang, X., Zhao, X., Zhu, P., Adler, Z., Wu, Z.-Y., Liu, Y., & Wang, H.
- Venue
- Nature Communications
- Published
- 2022-05-24
- Volume
- 13
- Issue
- 1
- Pages
- 2880-2880
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4281386070
- Cited by
- 316
- References
- 41
- FWCI
- 11.48
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhang, X., Zhao, X., Zhu, P., Adler, Z., Wu, Z.-Y., Liu, Y., & Wang, H. (2022). Electrochemical oxygen reduction to hydrogen peroxide at practical rates in strong acidic media. Nature Communications. https://doi.org/10.1038/s41467-022-30337-0
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