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Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light
Open accessAbstract
Methane (CH 4 ) oxidation to high value chemicals under mild conditions through photocatalysis is a sustainable and appealing pathway, nevertheless confronting the critical issues regarding both conversion and selectivity. Herein, under visible irradiation (420 nm), the synergy of palladium (Pd) atom cocatalyst and oxygen vacancies (OVs) on In 2 O 3 nanorods enables superior photocatalytic CH 4 activation by O 2 . The optimized catalyst reaches ca. 100 μmol h −1 of C1 oxygenates, with a selectivity of primary products (CH 3 OH and CH 3 OOH) up to 82.5%. Mechanism investigation elucidates that such superior photocatalysis is induced by the dedicated function of Pd single atoms and oxygen vacancies on boosting hole and electron transfer, respectively. O 2 is proven to be the only oxygen source for CH 3 OH production, while H 2 O acts as the promoter for efficient CH 4 activation through ·OH production and facilitates product desorption as indicated by DFT modeling. This work thus provides new understandings on simultaneous regulation of both activity and selectivity by the synergy of single atom cocatalysts and oxygen vacancies.
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Wang, Q., Hisatomi, T., Jia, Q., Tokudome, H., Zhong, M., Wang, C., Pan, Z., Takata, T., Nakabayashi, M., Shibata, N., et al. (2016) · Nature Materials · doi:10.1038/nmat4589 · Cited by 1,684
Cited by
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
Jiang, W., Loh, H., Low, B. Q. L., Zhu, H., Low, J., Heng, J. Z. X., Tang, K. Y., Li, Z., Loh, X. J., Ye, E., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122079 · Cited by 401
Enabling Specific Photocatalytic Methane Oxidation by Controlling Free Radical Type
Jiang, Y., Li, S., Wang, S., Zhang, Y., Long, C., Xie, J., Fan, X., Zhao, W., Xu, P., Fan, Y., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c13313 · Cited by 341
Zhang, Y., Li, Y., Xin, X., Wang, Y., Guo, P., Wang, R., Wang, B., Huang, W., Sobrido, A. J., & Li, X. (2023) · Nature Energy · doi:10.1038/s41560-023-01242-7 · Cited by 298
Metadata
- Authors
- Luo, L., Fu, L., Liu, H., Xu, Y., Xing, J., Chang, C.-R., Yang, D.-Y., & Tang, J.
- Venue
- Nature Communications
- Published
- 2022-05-25
- Volume
- 13
- Issue
- 1
- Pages
- 2930-2930
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4281493737
- Cited by
- 316
- References
- 1
- FWCI
- 11.88
- Type
- journal article
- Language
- en
- Open access
- gold
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- Luo, L., Fu, L., Liu, H., Xu, Y., Xing, J., Chang, C.-R., Yang, D.-Y., & Tang, J. (2022). Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light. Nature Communications. https://doi.org/10.1038/s41467-022-30434-0
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