The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
High entropy liquid electrolytes for lithium batteries
Open accessAbstract
High-entropy alloys/compounds have large configurational entropy by introducing multiple components, showing improved functional properties that exceed those of conventional materials. However, how increasing entropy impacts the thermodynamic/kinetic properties in liquids that are ambiguous. Here we show this strategy in liquid electrolytes for rechargeable lithium batteries, demonstrating the substantial impact of raising the entropy of electrolytes by introducing multiple salts. Unlike all liquid electrolytes so far reported, the participation of several anionic groups in this electrolyte induces a larger diversity in solvation structures, unexpectedly decreasing solvation strengths between lithium ions and solvents/anions, facilitating lithium-ion diffusivity and the formation of stable interphase passivation layers. In comparison to the single-salt electrolytes, a low-concentration dimethyl ether electrolyte with four salts shows an enhanced cycling stability and rate capability. These findings, rationalized by the fundamental relationship between entropy-dominated solvation structures and ion transport, bring forward high-entropy electrolytes as a composition-rich and unexplored space for lithium batteries and beyond.
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Clarifying the four core effects of high-entropy materials
Hsu, W.-L., Tsai, C.-W., Yeh, A.-C., & Yeh, J.-W. (2024) · Nature Reviews Chemistry · doi:10.1038/s41570-024-00602-5 · Cited by 928
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The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries
Zheng, W., Liang, G., Liu, Q., Li, J., Yuwono, J. A., Zhang, S., Peterson, V. K., & Guo, Z. (2023) · Joule · doi:10.1016/j.joule.2023.10.016 · Cited by 279
Metadata
- Authors
- Wang, Q., Zhao, C., Wang, J., Yao, Z., Wang, S., Kumar, S. G. H., Ganapathy, S., Eustace, S., Bai, X., Li, B., & Wagemaker, M.
- Venue
- Nature Communications
- Published
- 2023-01-27
- Volume
- 14
- Issue
- 1
- Pages
- 440-440
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4319986673
- Cited by
- 299
- References
- 47
- FWCI
- 21.92
- Type
- journal article
- Language
- en
- Open access
- gold
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