The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Lamella-heterostructured nanoporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride electrodes as stable catalysts for oxygen evolution
Open accessAbstract
Developing robust nonprecious-metal electrocatalysts with high activity towards sluggish oxygen-evolution reaction is paramount for large-scale hydrogen production via electrochemical water splitting. Here we report that self-supported laminate composite electrodes composed of alternating nanoporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride (FeCo/CeO 2−xNx) heterolamellas hold great promise as highly efficient electrocatalysts for alkaline oxygen-evolution reaction. By virtue of three-dimensional nanoporous architecture to offer abundant and accessible electroactive CoFeOOH/CeO 2−xNx heterostructure interfaces through facilitating electron transfer and mass transport, nanoporous FeCo/CeO 2−xNx composite electrodes exhibit superior oxygen-evolution electrocatalysis in 1 M KOH, with ultralow Tafel slope of ~33 mV dec−1. At overpotential of as low as 360 mV, they reach >3900 mA cm−2 and retain exceptional stability at ~1900 mA cm−2 for >1000 h, outperforming commercial RuO 2 and some representative oxygen-evolution-reaction catalysts recently reported. These electrochemical properties make them attractive candidates as oxygen-evolution-reaction electrocatalysts in electrolysis of water for large-scale hydrogen generation.
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Cites
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Cited by
Song, H., Yong, X., Waterhouse, G. I. N., Yu, J., Wang, H., Cai, J., Tang, Z., Yang, B., Chang, J., & Lu, S. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c06182 · Cited by 280
Unlocking Efficiency: Minimizing Energy Loss in Electrocatalysts for Water Splitting
Li, W., Liu, Y., Azam, A., Liu, Y., Yang, J., Wang, D., Sorrell, C. C., Zhao, C., & Li, S. (2024) · Advanced Materials · doi:10.1002/adma.202404658 · Cited by 162
Self-citationA review of efficient electrocatalysts for the oxygen evolution reaction at large current density
Yao, Y., Lyu, J., Li, X., Chen, C., Verpoort, F., Wang, J., Pan, Z., & Kou, Z. (2024) · DeCarbon · doi:10.1016/j.decarb.2024.100062 · Cited by 111
Li, W., Gou, W., Zhang, L., Zhong, M., Ren, S., Yu, G., Wang, C., Chen, W., & Lu, X. (2024) · Chemical Science · doi:10.1039/d4sc02840f · Cited by 77
Qiao, P., Li, G., Xu, X., Wang, D., Wang, F., Xu, L., Lu, L., Cong, H., & Sun, M. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202421136 · Cited by 63
Metadata
- Authors
- Zeng, S.-P., Shi, H., Dai, T.-Y., Liu, Y., Wen, Z., Han, G.-F., Wang, T.-H., Zhang, W., Lang, X.-Y., Zheng, W.-T., & Jiang, Q.
- Venue
- Nature Communications
- Published
- 2023-03-31
- Volume
- 14
- Issue
- 1
- Pages
- 1811-1811
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4362469439
- Cited by
- 189
- References
- 8
- FWCI
- 8.85
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zeng, S.-P., Shi, H., Dai, T.-Y., Liu, Y., Wen, Z., Han, G.-F., Wang, T.-H., Zhang, W., Lang, X.-Y., Zheng, W.-T., & Jiang, Q. (2023). Lamella-heterostructured nanoporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride electrodes as stable catalysts for oxygen evolution. Nature Communications. https://doi.org/10.1038/s41467-023-37597-4
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