The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.
2D/3D heterojunction engineering at the buried interface towards high-performance inverted methylammonium-free perovskite solar cells
Open accessAbstract
The main bottlenecks limiting the photovoltaic performance and stability of inverted perovskite solar cells (PSCs) are trap-assisted non-radiative recombination losses and photochemical degradation at the interface between perovskite and charge-transport layers. We propose a strategy to manipulate the crystallization of methylammonium-free perovskite by incorporating a small amount of 2-aminoindan hydrochloride into the precursor inks. This additive also modulates carrier recombination and extraction dynamics at the buried interface via the formation of a bottom-up two-dimensional/three-dimensional heterojunction. The resultant inverted PSC achieves a power conversion efficiency of 25.12% (certified 24.6%) at laboratory scale (0.09 cm2) and 22.48% at a larger area (1 cm2) with negligible hysteresis. More importantly, the resulting unencapsulated devices show superior operational stability, maintaining >98% of their initial efficiency of >24% after 1,500 hours of continuous maximum power point tracking under simulated AM1.5 illumination. Meanwhile, the encapsulated devices retain >92% of initial performance for 1,200 hours under the damp-heat test (85 °C and 85% relative humidity). To prevent charge losses and degradation at the buried interface of inverted methylammonium-free perovskite solar cells, Li et al. form a 2D/3D perovskite structure using 2-aminoindan hydrochloride as an additive.
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Cites
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Cited by
Double-side 2D/3D heterojunctions for inverted perovskite solar cells
Azmi, R., Utomo, D. S., Vishal, B., Zhumagali, S., Dally, P., Risqi, A. M., Prasetio, A., Ugur, E., Cao, F., Imran, I. F., et al. (2024) · Nature · doi:10.1038/s41586-024-07189-3 · Cited by 452
Metadata
- Authors
- Li, H., Zhang, C., Gong, C., Zhang, D., Zhang, H., Zhuang, Q., Yu, X., Gong, S., Chen, X., Yang, J., Li, X., Li, R., Li, J., Zhou, J., Yang, H., Lin, Q., Chu, J., Grätzel, M., Chen, J., & Zang, Z.
- Venue
- Nature Energy
- Published
- 2023-07-06
- Volume
- 8
- Issue
- 9
- Pages
- 946-955
- ISSN
- 2058-7546 (ISSN-L)
- OpenAlex
- W4383341244
- Cited by
- 404
- References
- 51
- FWCI
- 29.61
- Type
- journal article
- Language
- en
- Open access
- green
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- Li, H., Zhang, C., Gong, C., Zhang, D., Zhang, H., Zhuang, Q., Yu, X., Gong, S., Chen, X., Yang, J., Li, X., Li, R., Li, J., Zhou, J., Yang, H., Lin, Q., Chu, J., Grätzel, M., Chen, J., & Zang, Z. (2023). 2D/3D heterojunction engineering at the buried interface towards high-performance inverted methylammonium-free perovskite solar cells. Nature Energy. https://doi.org/10.1038/s41560-023-01295-8
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