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Cited by 14Catalysis and Hydrodesulfurization StudiesIndustrial Gas Emission ControlIonic liquids properties and applications

The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.

One-Step Preparation of Deep Eutectic Solvents/Reduced Graphene Oxide Composite Materials for the Removal of Dibenzothiophene in Fuel Oil

Open access
Liu, Yue, Su, Xiaoping, Cui, Yingna, Zhou, Xin·2023·Scientific Reports
DOI 10.1038/s41598-023-28041-0PMC PMC9842677
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Abstract

Deep eutectic solvents (DES)/reduced graphene oxide (rGO) composite materials can remove dibenzothiophene (DBT) from fuel oil by adsorption desulfurization. However, the whole synthesis process is complicated, and the DES/rGO is high-cost and not strong enough, which limits its application in industry. Therefore, a one-step method to produce DES/rGO composite materials is proposed. The performance of desulfurization was studied and the feasibility of industrial application was analyzed. First, the proposed method can improve the single extraction efficiency to 94.8% without a complicated process. Secondly, the DES/rGO can also be reused and recycled. Third, the proposed method overcomes the inconvenient storage and transportation of liquid DES. Finally, the proposed method could effectively reduce the cost of desulphurization in the industry.

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Crossref · 10.1038/s41598-023-28041-0

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23 of 23 references verified0 citation errors · 0 not checkable

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Figures

Figure 1 The preparation of TBAC/ p-TsOH.
Figure 1 The preparation of TBAC/ p-TsOH.CC BY · PubMed Central
Figure 2 The effect of adding oxidant on extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).
Figure 2 The effect of adding oxidant on extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 3 The effect of different oxidants on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).
Figure 3 The effect of different oxidants on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 4 The effect of oxidant amount on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).
Figure 4 The effect of oxidant amount on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 5 The effect of different loading amounts of TBAC/2p-TsOH on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).
Figure 5 The effect of different loading amounts of TBAC/2p-TsOH on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 6 The effect of the amount of composite materials on the extraction efficiency (experimental conditions: 1600 mg/L sulphur content, 0.25 g H2O2, 25 °C, 800 rpm, 60 min).
Figure 6 The effect of the amount of composite materials on the extraction efficiency (experimental conditions: 1600 mg/L sulphur content, 0.25 g H2O2, 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 7 The effect of system temperature on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 800 rpm, 60 min).
Figure 7 The effect of system temperature on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 800 rpm, 60 min).CC BY · PubMed Central
Figure 8 The effect of extraction time on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm).
Figure 8 The effect of extraction time on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 800 rpm).CC BY · PubMed Central
Figure 9 The effect of rotation speed on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 60 min).
Figure 9 The effect of rotation speed on the extraction efficiency (experimental conditions: 1.2 g composite material, 0.5 g simulated oil (1600 mg/L sulphur content), 25 °C, 60 min).CC BY · PubMed Central
Figure 10 The effect of repeated use on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).
Figure 10 The effect of repeated use on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 11 The effect of recycling on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).
Figure 11 The effect of recycling on the extraction efficiency (experimental conditions: 1.2 g (TBAC/2p-TsOH)/rGO, 0.5 g simulated oil (1600 mg/L sulphur content), 0.25 g H2O2, 25 °C, 800 rpm, 60 min).CC BY · PubMed Central
Figure 12 TGA curve of DES/rGO and DES/rGO after desulfurization.
Figure 12 TGA curve of DES/rGO and DES/rGO after desulfurization.CC BY · PubMed Central
Figure 13 Infrared curve of DBT, DES/rGO, DES/rGO after desulfurization.
Figure 13 Infrared curve of DBT, DES/rGO, DES/rGO after desulfurization.CC BY · PubMed Central

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Metadata

Authors
Liu, Y., Su, X., Cui, Y., & Zhou, X.
Affiliations
Dalian University (CN)
Corresponding author
Liu, Yue
ORCID
Venue
Scientific Reports
Publisher
Springer Science and Business Media LLC
Published
2023-01-16
Volume
13
Issue
1
Pages
832-832
ISSN
2045-2322 (ISSN-L)
DOI
10.1038/s41598-023-28041-0
PMC
PMC9842677
OpenAlex
W4316469838
Cited by
14
References
23
Citations by year
2026: 3 · 2025: 5 · 2024: 4 · 2023: 2
FWCI
1.38
Type
journal article
Language
en
Open access
Licence
Locations
  • Scientific Reports (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
National Natural Science Foundation of China (21606031, 21473183)
Topics
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Hydrodesulfurization Studies
  • Physical Sciences › Environmental Science › Environmental Engineering › Industrial Gas Emission Control
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Keywords
deep eutectic solvents, reduced graphene oxide, composite adsorbent, dibenzothiophene, fuel oil desulfurization, adsorptive desulfurization, one-step synthesis, adsorbent reusability

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.