Spiro-salen catalysts enable the chemical synthesis of stereoregular polyhydroxyalkanoates
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Metal-catalyzed stereoselective ring-opening polymerization is a powerful strategy to access P3HB with tunable stereomicrostructures and to incorporate designer comonomers.
“In particular, metal-catalyzed stereoselective ring-opening polymerization (ROP) has emerged as a powerful strategy to access P3HB with tunable stereomicrostructures [13-18] and for incorporating designer comonomers [19-23]”
From Functional and Network PHAs via Stereoselective Polymerization and Tailored Post‐Transformation (2026) · cites this paper as [20]
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References 59 · Cited by 105
- Authors
- Huang, H.-Y., Xiong, W., Huang, Y.-T., Li, K., Cai, Z., & Zhu, J.-B.
- Affiliations
- Sichuan University (CN)
- Corresponding author
- Zhu, Jian-Bo
- Venue
- Nature Catalysis
- Published
- 2023-08-10
- Volume
- 6
- Issue
- 8
- Pages
- 720-728
- ISSN
- 2520-1158 (ISSN-L)
- OpenAlex
- W4385737642
- Cited by
- 105
- References
- 59
- Citations by year
- 2026: 20 · 2025: 40 · 2024: 43 · 2023: 2
- FWCI
- 6.72
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Nature Catalysis (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Keywords
- yttrium complexes, stereoselective ring-opening polymerization, polyhydroxyalkanoates, polyhydroxybutyrate, poly(3-hydroxybutyrate-co-3-hydroxyvalerate), syndiotactic polymers, isotactic polymers, β-butyrolactone, biodegradable polymers
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