The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Large-range Control of the Microstructures and Properties of Three-dimensional Porous Graphene
Open accessAbstract
Graphene-based three-dimensional porous macrostructures are believed of great importance in various applications, e.g. supercapacitors, photovoltaic cells, sensors and high-efficiency sorbents. However, to precisely control the microstructures and properties of this material to meet different application requirements in industrial practice remains challenging. We herein propose a facile and highly effective strategy for large-range tailoring the porous architecture and its properties by a modified freeze casting process. The pore sizes and wall thicknesses of the porous graphene can be gradually tuned by 80 times (from 10 to 800 μm) and 4000 times (from 20 nm to 80 μm), respectively. The property experiences the changing from hydrophilic to hydrophobic, with the Young's Modulus varying by 15 times. The fundamental principle of the porous microstructure evolution is discussed in detail. Our results demonstrate a very convenient and general protocol to finely tailor the structure and further benefit the various applications of porous graphene.
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Cites
Synthesis of Graphene Aerogel with High Electrical Conductivity
Worsley, M. A., Pauzauskie, P. J., Olson, T. Y., Biener, J., Satcher, J. H., & Baumann, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1072299 · Cited by 1,216
Ultralight Multiwalled Carbon Nanotube Aerogel
Zou, J., Liu, J., Karakoti, A. S., Kumar, A., Joung, D., Li, Q., Khondaker, S. I., Seal, S., & Zhai, L. (2010) · ACS Nano · doi:10.1021/nn102246a · Cited by 509
Graphene Hydrogels Deposited in Nickel Foams for High‐Rate Electrochemical Capacitors
Chen, J., Sheng, K., Luo, P., Li, C., & Shi, G. (2012) · Advanced Materials · doi:10.1002/adma.201201978 · Cited by 438
Freeze casting of porous materials: review of critical factors in microstructure evolution
Li, W. L., Lu, K., & Walz, J. Y. (2012) · International Materials Reviews · doi:10.1179/1743280411y.0000000011 · Cited by 372
Cited by
Shao, G., Hanaor, D. A. H., Shen, X., & Gurlo, A. (2020) · Advanced Materials · doi:10.1002/adma.201907176 · Cited by 871
3D Graphene Materials: From Understanding to Design and Synthesis Control
Sun, Z., Fang, S., & Hu, Y. H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00083 · Cited by 543
Highly Compressible Macroporous Graphene Monoliths via an Improved Hydrothermal Process
Li, Y., Chen, J., Huang, L., Li, C., Hong, J., & Shi, G. (2014) · Advanced Materials · doi:10.1002/adma.201400657 · Cited by 379
Three-dimensional macro-structures of two-dimensional nanomaterials
Shehzad, K., Xu, Y., Gao, C., & Duan, X. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00218h · Cited by 357
Yang, J., Tang, L.-S., Bao, R.-Y., Bai, L., Liu, Z.-Y., Yang, W., Xie, B.-H., & Yang, M.-B. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta08454k · Cited by 255
Metadata
- Authors
- Xie, X., Zhou, Y., Bi, H., Yin, K., Wan, S., & Sun, L.
- Venue
- Scientific Reports
- Published
- 2013-07-02
- Volume
- 3
- Issue
- 1
- Pages
- 2117-2117
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2110360886
- Cited by
- 190
- References
- 4
- FWCI
- 7.55
- Type
- journal article
- Language
- en
- Open access
- gold
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