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The First Tandem, All-exciplex-based WOLED
Open accessAbstract
Exploiting our recently developed bilayer interface methodology, together with a new wide energy-gap, low LUMO acceptor (A) and the designated donor (D) layers, we succeeded in fabricating an exciplex-based organic light-emitting diode (OLED) systematically tuned from blue to red. Further optimization rendered a record-high blue exciplex OLED with η(ext) of 8%. We then constructed a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies η(ext): 11.6%, η(c): 27.7 cd A(-1), and η(p): 15.8 ml W(-1) with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer D/A (1:1) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs.
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Cites
The energy gap law for radiationless transitions in large molecules
Englman, R., & Jortner, J. (1970) · Molecular Physics · doi:10.1080/00268977000100171 · Cited by 2,778
Cited by
Purely Organic Thermally Activated Delayed Fluorescence Materials for Organic Light‐Emitting Diodes
Wong, M. Y., & Zysman‐Colman, E. (2017) · Advanced Materials · doi:10.1002/adma.201605444 · Cited by 2,050
Exciplex: An Intermolecular Charge-Transfer Approach for TADF
Sarma, M., & Wong, K.-T. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b18318 · Cited by 398
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Metadata
- Authors
- Hung, W.-Y., Fang, G.-C., Lin, S.-W., Cheng, S.-H., Wong, K.-T., Kuo, T.-Y., & Chou, P.-T.
- Venue
- Scientific Reports
- Published
- 2014-06-04
- Volume
- 4
- Issue
- 1
- Pages
- 5161-5161
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W1964188875
- Cited by
- 260
- References
- 1
- FWCI
- 12.73
- Type
- journal article
- Language
- en
- Open access
- gold
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