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High-efficient thermoelectric materials: The case of orthorhombic IV-VI compounds

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Ding, Guangqian, Gao, Guoying, Yao, Kailun·2015·Scientific Reports

Abstract

Improving the thermoelectric efficiency is one of the greatest challenges in materials science. The recent discovery of excellent thermoelectric performance in simple orthorhombic SnSe crystal offers new promise in this prospect [Zhao et al. Nature 508, 373 (2014)]. By calculating the thermoelectric properties of orthorhombic IV-VI compounds GeS,GeSe,SnS and SnSe based on the first-principles combined with the Boltzmann transport theory, we show that the Seebeck coefficient, electrical conductivity and thermal conductivity of orthorhombic SnSe are in agreement with the recent experiment. Importantly, GeS, GeSe and SnS exhibit comparative thermoelectric performance compared to SnSe. Especially, the Seebeck coefficients of GeS, GeSe and SnS are even larger than that of SnSe under the studied carrier concentration and temperature region. We also use the Cahill's model to estimate the lattice thermal conductivities at the room temperature. The large Seebeck coefficients, high power factors and low thermal conductivities make these four orthorhombic IV-VI compounds promising candidates for high-efficient thermoelectric materials.

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Metadata

Authors
Ding, G., Gao, G., & Yao, K.
Venue
Scientific Reports
Published
2015-06-05
Volume
5
Issue
1
Pages
9567-9567
ISSN
2045-2322 (ISSN-L)
OpenAlex
W1527803044
Cited by
264
References
22
FWCI
10.39
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: High-efficient thermoelectric materials: The case of orthorhombic IV-VI compounds. https://app.cochat.ai/papers/10.1038/srep09567
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Ding, G., Gao, G., & Yao, K. (2015). High-efficient thermoelectric materials: The case of orthorhombic IV-VI compounds. Scientific Reports. https://doi.org/10.1038/srep09567

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