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Efficient removal of crystal violet using Fe3O4-coated biochar: the role of the Fe3O4 nanoparticles and modeling study their adsorption behavior

Open access
Sun, Pengfei, Hui, Cai, Azim Khan, Rashid, Du, Jingting, Zhang, Qichun, Zhao, Yu-Hua·2015·Scientific Reports

Abstract

Biochar shows great promise for use in adsorbing pollutants. However, a process for enhancing its adsorption capacity and re-collection efficiency is yet to be further developed. Hence, in this study, we developed a type of biochar coated with magnetic Fe 3 O 4 nanoparticles (i.e., magnetic biochar (MBC)) and assessed its use for crystal violet (CV) adsorption as well as its recycling potential. The coating of Fe 3 O 4 nanoparticles, which was not only on the surface, but also in the interior of biochar, performed two functions. Firstly, it produced a saturation magnetization of 61.48 emu/g, which enabled the biochar being efficiently re-collected using a magnet. Secondly, it significantly enhanced the adsorption capacity of the biochar (from 80.36 to 99.19 mg/g). The adsorption capacity of the MBC was determined to be the largest by so far (349.40 mg/g) for an initial CV concentration of 400 mg/L, pH of 6.0 and temperature of 40 °C and the adsorption capacity of re-collected MBC was 73.31 mg/g. The adsorption of CV by the MBC was found to be a spontaneous and endothermic physical process in which the intraparticle diffusion was the limiting step. These findings inspire us to use other similar materials to tackle the menace of pollutions.

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Metadata

Authors
Sun, P., Hui, C., Azim Khan, R., Du, J., Zhang, Q., & Zhao, Y.-H.
Venue
Scientific Reports
Published
2015-07-29
Volume
5
Issue
1
Pages
12638-12638
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2410207777
Cited by
217
References
3
FWCI
11.15
Type
journal article
Language
en
Open access
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CoChat. (2026). Citation check: Efficient removal of crystal violet using Fe3O4-coated biochar: the role of the Fe3O4 nanoparticles and modeling study their adsorption behavior. https://app.cochat.ai/papers/10.1038/srep12638
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Sun, P., Hui, C., Azim Khan, R., Du, J., Zhang, Q., & Zhao, Y.-H. (2015). Efficient removal of crystal violet using Fe3O4-coated biochar: the role of the Fe3O4 nanoparticles and modeling study their adsorption behavior. Scientific Reports. https://doi.org/10.1038/srep12638

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