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Strategies to improve the epoxidation activity and selectivity of Ti-MCM-41
Abstract
Two strategies to improve the catalytic activity of Ti-MCM-41 materials in the epoxidation of olefins are described; the first approach involves silylation of the surface of Ti-MCM-41 which produces a very hydrophobic catalyst whereas the second approach is based on removal of water from the reaction media; the increase in activity is not due to a change in the intrinsic activity of the Ti sites, but rather to a decrease of the catalyst deactivation by reducing the formation of diols produced by ring opening of the epoxide.
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Citations
Cited by
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Self-citationSOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica
Anwander, R. (2001) · Chemistry of Materials · doi:10.1021/cm0111534 · Cited by 320
Metadata
- Authors
- Corma, A., Domine, M., Gaona, J. A., Jordá, J. L., Navarro, M. T., Rey, F., Pérez-Pariente, J., Tsuji, J., McCulloch, B., & Nemeth, L. T.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1998
- Issue
- 20
- Pages
- 2211-2212
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1976229780
- Cited by
- 216
- References
- 0
- FWCI
- 8.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Strategies to improve the epoxidation activity and selectivity of Ti-MCM-41. https://app.cochat.ai/papers/10.1039/a806702c
- The paper
- Corma, A., Domine, M., Gaona, J. A., Jordá, J. L., Navarro, M. T., Rey, F., Pérez-Pariente, J., Tsuji, J., McCulloch, B., & Nemeth, L. T. (1998). Strategies to improve the epoxidation activity and selectivity of Ti-MCM-41. Chemical Communications. https://doi.org/10.1039/a806702c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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