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Diels–Alder reactions in ionic liquids
Abstract
Diels–Alder reactions in neutral ionic liquids (such as 1-butyl-3-methylimidazolium trifluoromethanesulfonate, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, and 1-butyl-3-methyl-imidazolium lactate) are reported. Rate enhancements and selectivities similar to those of reactions performed in lithium perchlorate–diethyl ether mixtures have been observed. As the ionic liquids used have no measurable vapour pressure, are thermally robust, will tolerate impurities such as water, and are recyclable, it is envisaged that these systems could be used on an industrial scale.
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Citations
Cited by
Ionic liquids: solvent properties and organic reactivity
Chiappe, C., & Pieraccini, D. (2005) · Journal of Physical Organic Chemistry · doi:10.1002/poc.863 · Cited by 1,169
Ionic liquids: applications in catalysis
Zhao, D., Wu, M., Kou, Y., & Min, E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00541-7 · Cited by 1,049
Use of ionic liquids as ‘green’ solvents for extractions
Zhao, H., Xia, S., & Ma, P. (2005) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.1333 · Cited by 873
Toxicity and biodegradability of imidazolium ionic liquids
Romero, A., Santos, A., Tojo, J., & Rodríguez, A. (2008) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2007.10.079 · Cited by 713
Ionic liquids and deep eutectic mixtures: Sustainable solvents for extraction processes
Pena‐Pereira, F., & Namieśnik, J. (2014) · ChemSusChem · doi:10.1002/cssc.201301192 · Cited by 432
Metadata
- Authors
- Earle, M. J., McCormac, P. B., & Seddon, K. R.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1999
- Volume
- 1
- Issue
- 1
- Pages
- 23-25
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1922431434
- Cited by
- 513
- References
- 0
- FWCI
- 9.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Earle, M. J., McCormac, P. B., & Seddon, K. R. (1999). Diels–Alder reactions in ionic liquids. Green Chemistry. https://doi.org/10.1039/a808052f
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