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Bent metallocenes revisited
Abstract
The orbital structure of bent metallocenes and how their geometry depends on the number of d electrons are described. Bonding by a metallocene unit is exemplified by reference to the known hydrides. The reactivity of metallocene derivatives is illustrated with particular emphasis on the differences between ansa-bridged and unbridged compounds; the reactions include ring opening polymerisation of ferrocenophanes, elimination from and addition to Group 6 metallocene derivatives and Ziegler–Natta polymerisation of olefins by Group 4 metallocenes.
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Citations
Cited by
Complementarity of QTAIM and MO theory in the study of bonding in donor–acceptor complexes
Cortés-Guzmán, F., & Bader, R. F. W. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.08.022 · Cited by 579
Polyferrocenylsilanes: synthesis, properties, and applications
Hailes, R. L. N., Oliver, A. M., Gwyther, J., Whittell, G. R., & Manners, I. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00155f · Cited by 317
Barros, N., Mountford, P., Guillaume, S. M., & Maron, L. (2008) · Chemistry – A European Journal · doi:10.1002/chem.200800377 · Cited by 73
Metadata
- Authors
- C. Green, J.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1998
- Volume
- 27
- Issue
- 4
- Pages
- 263
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2017794085
- Cited by
- 238
- References
- 0
- FWCI
- 1.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- C. Green, J. (1998). Bent metallocenes revisited. Chemical Society Reviews. https://doi.org/10.1039/a827263z
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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