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Systematic XPS studies of metal oxides, hydroxides and peroxides
Abstract
The results of a systematic XPS study, under high controlled conditions, of different basic oxides of transition metals, alkali and alkaline-earth metals are presented; the XPS data of some hydroxides and peroxides are also reported. Variations of the O 1s binding energies are analysed and one point of interest is the large binding energy scale obtained for O 1s peaks all associated with a ‘‘2− ’’ formal charge. Through extended Hückel theory-tight binding (EHT-TB) calculations, attempts are made to rationalize the observed variations. The results illustrate the significant differences between real charges on oxygen atoms in transition metal and alkaline-earth oxides.
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Cited by
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Wang, Y., Yang, R., Ding, Y., Zhang, B., Li, H., Bai, B., Li, M., Cui, Y., Xiao, J., & Wu, Z.-S. (2023) · Nature Communications · doi:10.1038/s41467-023-37008-8 · Cited by 547
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Metadata
- Authors
- Dupin, J.-C., Gonbeau, D., Vinatier, P., & Levasseur, A.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2000
- Volume
- 2
- Issue
- 6
- Pages
- 1319-1324
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2058273255
- Cited by
- 2,247
- References
- 0
- FWCI
- 3.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dupin, J.-C., Gonbeau, D., Vinatier, P., & Levasseur, A. (2000). Systematic XPS studies of metal oxides, hydroxides and peroxides. Physical Chemistry Chemical Physics. https://doi.org/10.1039/a908800h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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