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Cited by 214

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Towards nanostructured arrays of single molecule magnets: new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis †

Goodwin, Jeremy C., Sessoli, Roberta, Gatteschi, Dante, Wernsdorfer, Wolfgang, Powell, Annie K., Heath, Sarah L.·2000·Journal of the Chemical Society, Dalton Transactions

Abstract

Ligands of general formula N(CHRCH2OH)(CH2CO2H)2 have been used to capture portions of the Fe(OH)2+ lattice to give particles containing up to nineteen magnetically coupled iron(III) centres. If R = Me or Et, lattices containing only Fe19 clusters result and single crystal X-ray diffraction shows that these are arranged in tilted stacks. These clusters act as single molecule magnets, pointing the way forward to engineering ordered arrays of magnetic particles. The packing of such materials is independent of the counter anion, NO3− or Cl−, used.

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Metadata

Authors
Goodwin, J. C., Sessoli, R., Gatteschi, D., Wernsdorfer, W., Powell, A. K., & Heath, S. L.
Venue
Journal of the Chemical Society, Dalton Transactions
Published
2000
Issue
12
Pages
1835-1840
ISSN
  • 1364-5447 (ISSN-L)
  • 1470-479X
OpenAlex
W2014258095
Cited by
214
References
1
FWCI
9.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Towards nanostructured arrays of single molecule magnets: new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis †. https://app.cochat.ai/papers/10.1039/b002135k
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Goodwin, J. C., Sessoli, R., Gatteschi, D., Wernsdorfer, W., Powell, A. K., & Heath, S. L. (2000). Towards nanostructured arrays of single molecule magnets: new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis †. Journal of the Chemical Society, Dalton Transactions. https://doi.org/10.1039/b002135k

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