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A net-based approach to coordination polymers †
Abstract
True crystal engineering of coordination polymers with useful structure-based properties by design remains a distant prospect. The exploratory, experimental net-based approach to the construction of coordination polymers described in this article has provided a few examples of structures obtained by design, but also serendipitously revealed numbers of unprecedented and interesting structures that were totally unexpected. Further work with coordination polymers can confidently be expected to provide many similar surprises. It is proposed that carefully designed connecting ligands capable of binding metal centres strongly and predictably at chelating sites may afford improved structural control in network assembly and more robust network structures.
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Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Structural diversity and chemical trends in hybrid inorganic–organic framework materials
Cheetham, A. K., Rao, C. N. R., & Feller, R. K. (2006) · Chem. Commun. · doi:10.1039/b610264f · Cited by 1,082
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
Tanabe, K. K., Wang, Z., & Cohen, S. M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801848j · Cited by 386
Coordination polymers and metal–organic frameworks based on poly(pyrazole)-containing ligands
Pettinari, C., Tăbăcaru, A., & Galli, S. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.08.005 · Cited by 269
Metadata
- Authors
- Robson, R.
- Venue
- Journal of the Chemical Society, Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2000
- Issue
- 21
- Pages
- 3735-3744
- ISSN
- 1364-5447 (ISSN-L)
- 1470-479X
- OpenAlex
- W2099497386
- Cited by
- 726
- References
- 0
- FWCI
- 23.07
- Type
- journal article
- Language
- en
- Open access
- closed
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