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Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid–ionic liquid biphasic mixtures
Abstract
Rhodium complexes of [1-propyl-3-methylimidazolium]2 [PhP(C6H4SO3-3)2] dissolved in the ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate catalyse the hydroformylation of oct-1-ene at a constant rate for >20 h in a continuous flow process in which the substrate, gases and products are transported in and out of the reactor dissolved in scCO2; <1 ppm rhodium is present in the collected product.
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Cited by
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Use of ionic liquids as ‘green’ solvents for extractions
Zhao, H., Xia, S., & Ma, P. (2005) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.1333 · Cited by 873
Giernoth, R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905981 · Cited by 746
Jessop, P. G., & Subramaniam, B. (2007) · Chemical Reviews · doi:10.1021/cr040199o · Cited by 561
Kornpointner, C., Sainz Martinez, A., Schnürch, M., Halbwirth, H., & Bica-Schröder, K. (2021) · Green Chemistry · doi:10.1039/d1gc03516a · Cited by 28
Metadata
- Authors
- Sellin, M. F., Webb, P. B., & Cole-Hamilton, D. J.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2001
- Issue
- 8
- Pages
- 781-782
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1979015961
- Cited by
- 214
- References
- 0
- FWCI
- 14.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sellin, M. F., Webb, P. B., & Cole-Hamilton, D. J. (2001). Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid–ionic liquid biphasic mixtures. Chemical Communications. https://doi.org/10.1039/b101046h
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