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Rhodium-catalyzed formation of boron–nitrogen bonds: a mild route to cyclic aminoboranes and borazines
Abstract
Secondary amine–borane adducts R2NH·BH3, which are stable to H2 elimination below 100 °C, undergo efficient catalytic dehydrocoupling at 25–45 °C in the presence of RhI or RhIII complexes to quantitatively form cyclic aminoboranes [NR2–BH2]2 (1: R = Me or 2: cyclo-C4H8); under similarly mild conditions, the analogous adducts NH3·BH3 and MeNH2·BH3 yield borazines [RN–BH]3 (3: R = H or 4: R = Me) in yields limited by intermolecular coupling reactions.
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Citations
Cited by
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Self-citationNi1-xPtx (x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
Cheng, F., Ma, H., Li, Y., & Chen, J. (2007) · Inorganic Chemistry · doi:10.1021/ic061712e · Cited by 349
Metadata
- Authors
- Jaska, C. A., Temple, K., Lough, A. J., & Manners, I.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2001
- Issue
- 11
- Pages
- 962-963
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2049737907
- Cited by
- 253
- References
- 0
- FWCI
- 3.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jaska, C. A., Temple, K., Lough, A. J., & Manners, I. (2001). Rhodium-catalyzed formation of boron–nitrogen bonds: a mild route to cyclic aminoboranes and borazines. Chemical Communications. https://doi.org/10.1039/b102361f
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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