The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Fullerene–porphyrin architectures; photosynthetic antenna and reaction center models
Abstract
Fullerenes and porphyrins are molecular architectures ideally suited for devising integrated, multicomponent model systems to transmit and process solar energy. Implementation of C60 as a 3-dimensional electron acceptor holds great expectations on account of their small reorganization energy in electron transfer reactions and has exerted a noteworthy impact on the improvement of light-induced charge-separation. This article describes how the specific compositions of porphyrin chromophores linked to C60--yielding artificial light harvesting antenna and reaction center mimics--have been elegantly utilized to tune the electronic couplings between donor and acceptor sites and the total reorganization energy. Specifically, the effects that these parameters have on the rate, yield and lifetime of the energetic charge-separated states are considered.
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Cites
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Mimicking Photosynthetic Solar Energy Transduction
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Excited-State Properties of C60 Fullerene Derivatives
Guldi, D. M., & Prato, M. (2000) · Accounts of Chemical Research · doi:10.1021/ar990144m · Cited by 1,103
Self-citationFulleropyrrolidines: A Family of Full-Fledged Fullerene Derivatives
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C60-Based Electroactive Organofullerenes
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Echegoyen, L., & Echegoyen, L. E. (1998) · Accounts of Chemical Research · doi:10.1021/ar970138v · Cited by 770
Imahori, H., Tamaki, K., Guldi, D. M., Luo, C., Fujitsuka, M., Ito, O., Sakata, Y., & Fukuzumi, S. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003346i · Cited by 543
Self-citationCharge Separation in a Novel Artificial Photosynthetic Reaction Center Lives 380 ms
Imahori, H., Guldi, D. M., Tamaki, K., Yoshida, Y., Luo, C., Sakata, Y., & Fukuzumi, S. (2001) · Journal of the American Chemical Society · doi:10.1021/ja004123v · Cited by 519
Self-citationLinkage and Solvent Dependence of Photoinduced Electron Transfer in Zincporphyrin-C60 Dyads
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Cited by
Lessons from nature about solar light harvesting
Scholes, G. D., Fleming, G. R., Olaya-Castro, A., & van Grondelle, R. (2011) · Nature Chemistry · doi:10.1038/nchem.1145 · Cited by 1,915
Large π-Aromatic Molecules as Potential Sensitizers for Highly Efficient Dye-Sensitized Solar Cells
Imahori, H., Umeyama, T., & Ito, S. (2009) · Accounts of Chemical Research · doi:10.1021/ar900034t · Cited by 1,012
Synthetische molekulare Motoren und mechanische Maschinen
Kay, E. R., Leigh, D. A., & Zerbetto, F. (2007) · Angewandte Chemie · doi:10.1002/ange.200504313 · Cited by 624
Structural Aspects of Fullerene ChemistryA Journey through Fullerene Chirality
Thilgen, C., & Diederich, F. (2006) · Chemical Reviews · doi:10.1021/cr0505371 · Cited by 508
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Large face to face tetraphenylporphyrin/fullerene nanoaggregates. A DFT study
Castillo, U. J., Guadarrama, P., & Fomine, S. (2013) · Organic Electronics · doi:10.1016/j.orgel.2013.05.032 · Cited by 16
Metadata
- Authors
- Guldi, D. M.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2001-12-18
- Volume
- 31
- Issue
- 1
- Pages
- 22-36
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2069560513
- Cited by
- 963
- References
- 24
- FWCI
- 22.10
- Type
- journal article
- Language
- en
- Open access
- closed
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