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Atom transfer radical cyclisation reactions mediated by copper complexes
Abstract
This article describes recent advances in the use of copper complexes in mediating atom transfer radical cyclisation reactions (ATRC). Recent developments have included the design of activated complexes which mediate the cyclisation of tri-, di-, and mono-halo derived substrates at ambient temperatures. Using this methodology, cyclisation to give a variety of ring sizes (4-18 membered rings) has been demonstrated. In addition tandem and radical-polar crossover reactions have also been developed. The design of solid supported and perfluorous complexes that mediate cyclisations may make this approach to the synthesis of rings more attractive towards industrial applications.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Macromolecular Engineering by Atom Transfer Radical Polymerization
Matyjaszewski, K., & Tsarevsky, N. V. (2014) · Journal of the American Chemical Society · doi:10.1021/ja408069v · Cited by 1,159
Pintauer, T., & Matyjaszewski, K. (2008) · Chemical Society Reviews · doi:10.1039/b714578k · Cited by 745
Zhang, N., Samanta, S. R., Rosen, B. M., & Percec, V. (2014) · Chemical Reviews · doi:10.1021/cr400689s · Cited by 458
Metadata
- Authors
- Clark, A. J.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2001-12-03
- Volume
- 31
- Issue
- 1
- Pages
- 1-11
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W1993828969
- Cited by
- 351
- References
- 0
- FWCI
- 4.28
- Type
- journal article
- Language
- en
- Open access
- closed
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