The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
An investigation of the radiochemical stability of ionic liquids
Abstract
Ionic liquids have been considered for their potential applications within the nuclear fuel cycle. If ionic liquids are to be successful in their application as solvents for highly radioactive materials in any future process, there will be a requirement for them to be robust to high radiation doses. A preliminary assessment of the radiation stability of 1,3-dialkylimidazolium cation based ionic liquids containing nitrate and chloride anions has been performed. The results of radiolysis studies are reported, in which the samples were exposed to alpha radiation from a tandem Van der Graaff generator, beta radiation from a linear accelerator and gamma radiation from cobalt 60 sources. These results suggest that their stability is similar to that of benzene and that they are much more stable than mixtures of tributylphosphate and odourless kerosene under similar irradiation conditions. The radiolysis of 1,3-dialkylimidazolium cation based ionic liquids reflects their combination of the properties of a salt, an alkane and an aromatic. They appear to be relatively radiation resistant and there is certainly no major decomposition of the organic component.
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Citations
Cites
Ionic Liquids—New “Solutions” for Transition Metal Catalysis
Wasserscheid, P., & Keim, W. (2000) · Angewandte Chemie · doi:10.1002/1521-3773(20001103)39:21<3772::aid-anie3772>3.0.co;2-5 · Cited by 5,720
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Self-citationLIQUID/LIQUID EXTRACTION OF METAL IONS IN ROOM TEMPERATURE IONIC LIQUIDS
Visser, A. E., Swatloski, R. P., Griffin, S. T., Hartman, D. H., & Rogers, R. D. (2001) · Separation Science and Technology · doi:10.1081/ss-100103620 · Cited by 359
Reaction Kinetics in Ionic Liquids: Pulse Radiolysis Studies of 1-Butyl-3-methylimidazolium Salts
Behar, D., Gonzalez, C., & Neta, P. (2001) · The Journal of Physical Chemistry A · doi:10.1021/jp011405o · Cited by 161
Ionic Liquids: Novel Media for Characterization of Radical Ions
Marcinek, A., Zielonka, J., Gebicki, J. L., Gordon, C. M., & Dunkin, I. R. (2001) · The Journal of Physical Chemistry A · doi:10.1021/jp0117718 · Cited by 98
Cited by
INNOVATIVE APPLICATIONS OF IONIC LIQUIDS AS “GREEN” ENGINEERING LIQUIDS
Zhao, H. (2006) · Chemical Engineering Communications · doi:10.1080/00986440600586537 · Cited by 343
Metadata
- Authors
- Allen, D., Baston, G., Bradley, A. E., Gorman, T., Haile, A., Hamblett, I., Hatter, J. E., Healey, M. J. F., Hodgson, B., Lewin, R., Lovell, K. V., Newton, B., Pitner, W. R., Rooney, D. W., Sanders, D., Seddon, K. R., Sims, H. E., & Thied, R. C.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002-03-26
- Volume
- 4
- Issue
- 2
- Pages
- 152-158
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2022438335
- Cited by
- 261
- References
- 5
- FWCI
- 3.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Allen, D., Baston, G., Bradley, A. E., Gorman, T., Haile, A., Hamblett, I., Hatter, J. E., Healey, M. J. F., Hodgson, B., Lewin, R., Lovell, K. V., Newton, B., Pitner, W. R., Rooney, D. W., Sanders, D., Seddon, K. R., Sims, H. E., & Thied, R. C. (2002). An investigation of the radiochemical stability of ionic liquids. Green Chemistry. https://doi.org/10.1039/b111042j
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