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Confusion, inversion, and creation—a new spring from porphyrin chemistry
Abstract
This article mainly deals with the recent serendipity of novel porphyrin analogs such as N-confused porphyrin. The unique property of this ligand allows the formation of a variety of metal complexes. The important aspect of dynamic flipping (inversion), induced either by confusion or expansion of the macrocyclic core, that leads to the generation of new porphyrinoids, is emphasized. This review concludes with the recent progress on expanded porphyrins bearing confused, inverted, and fused pyrrole rings.
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Cited by
Expanded Porphyrins: Intriguing Structures, Electronic Properties, and Reactivities
Saito, S., & Osuka, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201003909 · Cited by 695
Self-citationChemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist
Tanaka, T., & Osuka, A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00371 · Cited by 490
Self-citationFigure Eights, Möbius Bands, and More: Conformation and Aromaticity of Porphyrinoids
Stępień, M., Sprutta, N., & Latos‐Grażyński, L. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201003353 · Cited by 481
Expanded porphyrins and aromaticity
Osuka, A., & Saito, S. (2011) · Chemical Communications · doi:10.1039/c1cc10534e · Cited by 273
Self-citationSankar, J., Mori, S., Saito, S., Rath, H., Suzuki, M., Inokuma, Y., Shinokubo, H., Suk Kim, K., Yoon, Z. S., Shin, J.-Y., et al. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801983d · Cited by 261
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Metadata
- Authors
- Furuta, H., Maeda, H., & Osuka, A.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002
- Issue
- 17
- Pages
- 1795-1804
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2148165926
- Cited by
- 368
- References
- 0
- FWCI
- 16.61
- Type
- journal article
- Language
- en
- Open access
- closed
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