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Nitrophenyl derivatives of pyrrole 2,5-diamides: structural behaviour, anion binding and colour change signalled deprotonationElectronic supplementary information (ESI) available: 1H NMR, 13C NMR and mass spectra for compounds 2 and 3, NMR anion titration profiles in DMSO-d6–0.5% water. See http://www.rsc.org/suppdata/ob/b2/b210848h/
Abstract
Two new pyrrole 2,5-diamide clefts have been synthesized containing 4-nitrophenyl or 3,5-dinitrophenyl groups appended to the amide positions. The 3,5-dinitrophenyl derivative has been shown to deprotonate in the presence of fluoride, which in acetonitrile solution, gives rise to a deep blue colour.
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Citations
Cited by
Fluorogenic and Chromogenic Chemosensors and Reagents for Anions
Martínez-Máñez, R., & Sancenón, F. (2003) · Chemical Reviews · doi:10.1021/cr010421e · Cited by 3,076
Gunnlaugsson, T., Glynn, M., Tocci (née Hussey), G. M., Kruger, P. E., & Pfeffer, F. M. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.08.017 · Cited by 1,257
Applications of Supramolecular Anion Recognition
Busschaert, N., Caltagirone, C., Van Rossom, W., & Gale, P. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00099 · Cited by 1,249
Self-citationFluorescence and Colorimetric Chemosensors for Fluoride-Ion Detection
Zhou, Y., Zhang, J. F., & Yoon, J. (2014) · Chemical Reviews · doi:10.1021/cr400352m · Cited by 1,072
Anion receptors based on organic frameworks: highlights from 2005 and 2006
Gale, P. A., García-Garrido, S. E., & Garric, J. (2008) · Chem. Soc. Rev. · doi:10.1039/b715825d · Cited by 782
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Metadata
- Authors
- Camiolo, S., Gale, P. A., Hursthouse, M. B., & Light, M. E.
- Venue
- Organic & Biomolecular Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003-01-28
- Volume
- 1
- Issue
- 4
- Pages
- 741-744
- ISSN
- 1477-0520 (ISSN-L)
- 1477-0539
- OpenAlex
- W2128216247
- Cited by
- 189
- References
- 0
- FWCI
- 8.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Nitrophenyl derivatives of pyrrole 2,5-diamides: structural behaviour, anion binding and colour change signalled deprotonationElectronic supplementary information (ESI) available: 1H NMR, 13C NMR and mass spectra for compounds 2 and 3, NMR anion titration profiles in DMSO-d6–0.5% water. See http://www.rsc.org/suppdata/ob/b2/b210848h/. https://app.cochat.ai/papers/10.1039/b210848h
- The paper
- Camiolo, S., Gale, P. A., Hursthouse, M. B., & Light, M. E. (2003). Nitrophenyl derivatives of pyrrole 2,5-diamides: structural behaviour, anion binding and colour change signalled deprotonationElectronic supplementary information (ESI) available: 1H NMR, 13C NMR and mass spectra for compounds 2 and 3, NMR anion titration profiles in DMSO-d6–0.5% water. See http://www.rsc.org/suppdata/ob/b2/b210848h/. Organic & Biomolecular Chemistry. https://doi.org/10.1039/b210848h
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