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Unique asymmetric catalysis of cis-? metal complexes of salen and its related Schiff-base ligands
Abstract
Complexes of chiral salen and its related tetradentate Schiff-base ligands adopt three different configurations, trans, cis-alpha and cis-beta. Of these complexes, trans-complexes have been widely used as catalysts for various asymmetric reactions. However, recent studies have disclosed that cis-beta metallosalen and its related complexes show unique asymmetric catalyses that cannot be achieved by trans-metallosalen complexes. The present article summarizes generation of cis-beta metallosalen and its related complexes, their structural features, and their application to asymmetric syntheses.
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Citations
Cites
Asymmetric Catalysis of Epoxide Ring-Opening Reactions
Jacobsen, E. N. (2000) · Accounts of Chemical Research · doi:10.1021/ar960061v · Cited by 1,261
Cited by
Baleizão, C., & Garcia, H. (2006) · Chemical Reviews · doi:10.1021/cr050973n · Cited by 697
Material Applications for Salen Frameworks
Wezenberg, S. J., & Kleij, A. W. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702468 · Cited by 289
Beament, B., Britton, D., Malcomson, T., Akien, G. R., Halcovitch, N. R., Coogan, M. P., & Platel, R. H. (2024) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03120 · Cited by 27
Metadata
- Authors
- Katsuki, T.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2004
- Volume
- 33
- Issue
- 7
- Pages
- 437
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2131219992
- Cited by
- 344
- References
- 1
- FWCI
- 11.65
- Type
- journal article
- Language
- en
- Open access
- closed
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