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Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation
Open accessAbstract
The solubility of hydrogen and the corresponding Henry coefficients for 11 ionic liquids have been determined in situ at 100 atm H2 pressure and are much lower than expected; attempts to correlate the solubility of hydrogen in the ionic liquids with the rate of reaction for the hydrogenation of benzene to cyclohexane in these solvents have been made.
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Citations
Cited by
Pârvulescu, V. I., & Hardacre, C. (2007) · Chemical Reviews · doi:10.1021/cr050948h · Cited by 2,377
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Giernoth, R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905981 · Cited by 746
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media
Moret, S., Dyson, P. J., & Laurenczy, G. (2014) · Nature Communications · doi:10.1038/ncomms5017 · Cited by 733
Self-citationJessop, P. G., & Subramaniam, B. (2007) · Chemical Reviews · doi:10.1021/cr040199o · Cited by 561
Metadata
- Authors
- Dyson, P. J., Laurenczy, G., André Ohlin, C., Vallance, J., & Welton, T.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003
- Issue
- 19
- Pages
- 2418-2419
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2151827740
- Cited by
- 178
- References
- 0
- FWCI
- 4.67
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation. https://app.cochat.ai/papers/10.1039/b308309h
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- Dyson, P. J., Laurenczy, G., André Ohlin, C., Vallance, J., & Welton, T. (2003). Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation. Chem. Commun. https://doi.org/10.1039/b308309h
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