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Evidence of an aggregative mechanism during the formation of silver nanowires in N,N-dimethylformamide
Abstract
A detailed high-resolution electron microscopy study of the formation of Ag nanowires by solvent reduction in N,N-dimethylformamide (DMF), in the presence of poly(vinylpyrrolidone) (PVP) at high temperature provided clear evidence that the nanowires grow through the oriented aggregation of precursor nanoparticles. The HRTEM images demonstrate that initially, icosahedral and cuboctahedral Ag nanoparticles are formed, which then self-assemble to form aligned stripes, and eventually fuse with each other to yield single crystalline nanowires. The nanoparticle aggregation only takes place through preferred facets of the original nanocrystals, and therefore intermediate twisted wires are observed.
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Cites
Growth of nanowire superlattice structures for nanoscale photonics and electronics
Gudiksen, M. S., Lauhon, L. J., Wang, J., Smith, D. C., & Lieber, C. M. (2002) · Nature · doi:10.1038/415617a · Cited by 2,709
Cited by
Controlling Mineral Morphologies and Structures in Biological and Synthetic Systems
Meldrum, F. C., & Cölfen, H. (2008) · Chemical Reviews · doi:10.1021/cr8002856 · Cited by 1,397
Baruah, B., Gabriel, G. J., Akbashev, M. J., & Booher, M. E. (2013) · Langmuir · doi:10.1021/la305068p · Cited by 391
Metadata
- Authors
- Giersig, M., Pastoriza-Santos, I., & Liz-Marzán, L. M.
- Venue
- J. Mater. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2004
- Volume
- 14
- Issue
- 4
- Pages
- 607-610
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W1950829839
- Cited by
- 180
- References
- 1
- FWCI
- 12.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Giersig, M., Pastoriza-Santos, I., & Liz-Marzán, L. M. (2004). Evidence of an aggregative mechanism during the formation of silver nanowires in N,N-dimethylformamide. J. Mater. Chem. https://doi.org/10.1039/b311454f
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