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Catalytic performance and properties of ceria based catalysts for cyclic carbonate synthesis from glycol and carbon dioxide
Abstract
Ceria based catalysts are very effective for the synthesis of cyclic carbonate such as ethylene carbonate (EC) and propylene carbonate (PC) by the reaction of CO2 with ethylene glycol and propylene glycol. In these reactions, polycarbonate and ethers (diethylene glycol and dipropylene glycol) were not detected under optimum reaction conditions. This indicates that the PC and EC formation over CeO2–ZrO2 catalysts is highly selective. Catalytic activity was much dependent on the composition and calcination temperature of catalysts. On the basis of catalyst characterization by means of surface area measurement, X-ray diffraction, thermogravimetric analysis, and temperature programmed desorption of NH3 and CO2, the relations between catalytic performance and properties are discussed.
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Citations
Cites
Reactive Applications of Cyclic Alkylene Carbonates
Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784
Cited by
Aresta, M., Dibenedetto, A., & Angelini, A. (2014) · Chemical Reviews · doi:10.1021/cr4002758 · Cited by 3,143
A short review of catalysis for CO2 conversion
Ma, J., Sun, N., Zhang, X., Zhao, N., Xiao, F., Wei, W., & Sun, Y. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.08.015 · Cited by 707
Non‐isocyanate polyurethanes: synthesis, properties, and applications
Rokicki, G., Parzuchowski, P. G., & Mazurek, M. (2015) · Polymers for Advanced Technologies · doi:10.1002/pat.3522 · Cited by 421
Ceria‐Based Solid Catalysts for Organic Chemistry
Vivier, L., & Duprez, D. (2010) · ChemSusChem · doi:10.1002/cssc.201000054 · Cited by 391
The direct transformation of carbon dioxide to organic carbonates over heterogeneous catalysts
Dai, W.-L., Luo, S.-L., Yin, S.-F., & Au, C.-T. (2009) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.06.045 · Cited by 366
Metadata
- Authors
- Tomishige, K., Yasuda, H., Yoshida, Y., Nurunnabi, M., Li, B., & Kunimori, K.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2004
- Volume
- 6
- Issue
- 4
- Pages
- 206
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1987995132
- Cited by
- 164
- References
- 1
- FWCI
- 4.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tomishige, K., Yasuda, H., Yoshida, Y., Nurunnabi, M., Li, B., & Kunimori, K. (2004). Catalytic performance and properties of ceria based catalysts for cyclic carbonate synthesis from glycol and carbon dioxide. Green Chemistry. https://doi.org/10.1039/b401215a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
