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Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites
Abstract
Carbon, and particularly graphite in its various forms, is an attractive electrode material. Two areas of particular interest are modified carbon electrodes and carbon nanotube electrodes. In this article we focus on the relationship between surface structure and electrochemical and chemical reactivity of electrodes based on these materials. We overview recent work in this area which has led us to believe that much of the catalytic activity, electron transfer and chemical reactivity of graphitic carbon electrodes is at surface defect sites, and in particular edge-plane-like defect sites. We also question the claimed special "catalytic" properties of carbon nanotube modified electrodes.
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Citations
Cited by
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Ambrosi, A., Chua, C. K., Bonanni, A., & Pumera, M. (2014) · Chemical Reviews · doi:10.1021/cr500023c · Cited by 1,208
Nitrogen-doped graphene and its electrochemical applications
Shao, Y., Zhang, S., Engelhard, M. H., Li, G., Shao, G., Wang, Y., Liu, J., Aksay, I. A., & Lin, Y. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00782j · Cited by 1,123
Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides
Chia, X., Eng, A. Y. S., Ambrosi, A., Tan, S. M., & Pumera, M. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00287 · Cited by 894
Counter electrodes in dye-sensitized solar cells
Wu, J., Lan, Z., Lin, J., Huang, M., Huang, Y., Fan, L., Luo, G., Lin, Y., Xie, Y., & Wei, Y. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00752j · Cited by 788
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Metadata
- Authors
- Banks, C. E., Davies, T. J., Wildgoose, G. G., & Compton, R. G.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 7
- Pages
- 829
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2126354289
- Cited by
- 1,023
- References
- 0
- FWCI
- 25.56
- Type
- journal article
- Language
- en
- Open access
- closed
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- Banks, C. E., Davies, T. J., Wildgoose, G. G., & Compton, R. G. (2005). Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites. Chemical Communications. https://doi.org/10.1039/b413177k
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
