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Linear π-conjugated systems derivatized with C60-fullerene as molecular heterojunctions for organic photovoltaics
Abstract
This tutorial review covers recent contributions in the area of linear pi-conjugated systems bound to fullerenes in view of their application as active materials in photovoltaic devices. The first part discusses the concepts of double-cable polymer and molecular hetero-junction and presents several examples of chemically or electrochemically synthesized C60-derivatized conjugated polymers. The second and main part of the article concerns the various classes of C60-derivatized pi-conjugated oligomers designed in view of their utilization in single-component photovoltaic devices. Thus, C60-containing pi-conjugated systems such as oligoarylenevinylenes, oligoaryleneethynylenes and oligothiophenes are discussed on the basis of the relationships between molecular structure, photophysical properties and performances of the derived photovoltaic devices. A brief last section presents some recent examples of surface-attached molecular hetero-junctions based on self-assembled monolayers and discusses possible routes for future research.
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Cited by
Charge Photogeneration in Organic Solar Cells
Clarke, T. M., & Durrant, J. R. (2010) · Chemical Reviews · doi:10.1021/cr900271s · Cited by 2,372
Small molecule semiconductors for high-efficiency organic photovoltaics
Lin, Y., Li, Y., & Zhan, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15313k · Cited by 1,751
Electrochemistry of Conducting Polymers—Persistent Models and New Concepts
Heinze, J., Frontana-Uribe, B. A., & Ludwigs, S. (2010) · Chemical Reviews · doi:10.1021/cr900226k · Cited by 1,258
Roquet, S., Cravino, A., Leriche, P., Alévêque, O., Frère, P., & Roncali, J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058178e · Cited by 787
Self-citationDastoor, P. C., McNeill, C. R., Frohne, H., Foster, C. J., Dean, B., Fell, C. J., Belcher, W. J., Campbell, W. M., Officer, D. L., Blake, I. M., et al. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp0748664 · Cited by 77
Metadata
- Authors
- Roncali, J.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Volume
- 34
- Issue
- 6
- Pages
- 483
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2140453622
- Cited by
- 258
- References
- 0
- FWCI
- 1.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Roncali, J. (2005). Linear π-conjugated systems derivatized with C60-fullerene as molecular heterojunctions for organic photovoltaics. Chemical Society Reviews. https://doi.org/10.1039/b415941c
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