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Secondary organic aerosols from anthropogenic and biogenic precursors
Abstract
Secondary organic aerosol (SOA) formation from the photooxidation of an anthropogenic (1,3,5-trimethylbenzene) and a biogenic (alpha-pinene) precursor was investigated at the new PSI smog chamber. The chemistry of the gas phase was followed by proton transfer reaction mass spectrometry, while the aerosol chemistry was investigated with aerosol mass spectrometry, ion chromatography, laser desorption ionization mass spectrometry, and infrared spectroscopy, along with volatility and hygroscopicity studies. Evidence for oligomer formation for SOA from both precursors was given by an increasing abundance of compounds with a high molecular weight (up to 1000 Da) and by an increasing thermal stability with increasing aging time. The results were compared to data obtained from ambient aerosol samples, revealing a number of similar features.
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Citations
Cited by
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics
Donahue, N. M., Robinson, A. L., Stanier, C. O., & Pandis, S. N. (2006) · Environmental Science & Technology · doi:10.1021/es052297c · Cited by 1,525
Koop, T., Bookhold, J., Shiraiwa, M., & Pöschl, U. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22617g · Cited by 785
The effect of physical and chemical aerosol properties on warm cloud droplet activation
McFiggans, G., Artaxo, P., Baltensperger, U., Coe, H., Facchini, M. C., Feingold, G., Fuzzi, S., Gysel, M., Laaksonen, A., Lohmann, U., et al. (2006) · Atmospheric Chemistry and Physics · doi:10.5194/acp-6-2593-2006 · Cited by 710
Self-citationClosure study between chemical composition and hygroscopic growth of aerosol particles during TORCH2
Gysel, M., Crosier, J., Topping, D. O., Whitehead, J. D., Bower, K. N., Cubison, M. J., Williams, P. I., Flynn, M. J., McFiggans, G. B., & Coe, H. (2007) · Atmospheric Chemistry and Physics · doi:10.5194/acp-7-6131-2007 · Cited by 334
Self-citationA review of the anthropogenic influence on biogenic secondary organic aerosol
Hoyle, C. R., Boy, M., Donahue, N. M., Fry, J. L., Glasius, M., Guenther, A., Hallar, A. G., Huff Hartz, K., Petters, M. D., Petäjä, T., et al. (2011) · Atmospheric Chemistry and Physics · doi:10.5194/acp-11-321-2011 · Cited by 306
Metadata
- Authors
- Baltensperger, U., Kalberer, M., Dommen, J., Paulsen, D., Alfarra, M. R., Coe, H., Fisseha, R., Gascho, A., Gysel, M., Nyeki, S., Sax, M., Steinbacher, M., Prevot, A. S. H., Sjögren, S., Weingartner, E., & Zenobi, R.
- Venue
- Faraday Discussions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Volume
- 130
- Pages
- 265
- ISSN
- 1359-6640 (ISSN-L)
- 1364-5498
- OpenAlex
- W2162475503
- Cited by
- 243
- References
- 0
- FWCI
- 14.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Secondary organic aerosols from anthropogenic and biogenic precursors. https://app.cochat.ai/papers/10.1039/b417367h
- The paper
- Baltensperger, U., Kalberer, M., Dommen, J., Paulsen, D., Alfarra, M. R., Coe, H., Fisseha, R., Gascho, A., Gysel, M., Nyeki, S., Sax, M., Steinbacher, M., Prevot, A. S. H., Sjögren, S., Weingartner, E., & Zenobi, R. (2005). Secondary organic aerosols from anthropogenic and biogenic precursors. Faraday Discussions. https://doi.org/10.1039/b417367h
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