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Enhanced photocatalytic formation of hydroxyl radicals on fluorinated TiO2

Mrowetz, Marta, Selli, Elena·2005·Physical Chemistry Chemical Physics

Abstract

Direct experimental evidence of the higher concentration of hydroxyl radicals generated on fluorinated titanium dioxide (F-TiO2) under irradiation was obtained by spin-trapping EPR measurements. The faster photoinduced bleaching of the azo dye Acid Red 1 (AR1) observed in the presence of F-TiO2 was explained by the high affinity of the azo double bond towards *OH radicals. Moreover, the pronounced decrease of the AR1 bleaching rate by addition of 2-propanol, as hydroxyl radicals scavenger, on F-TiO2 and not on naked TiO2 demonstrated that on fluorinated titania AR1 is mainly degraded via *OH radical attack.

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Metadata

Authors
Mrowetz, M., & Selli, E.
Venue
Physical Chemistry Chemical Physics
Published
2005
Volume
7
Issue
6
Pages
1100
ISSN
  • 1463-9076 (ISSN-L)
  • 1463-9084
OpenAlex
W2158233043
Cited by
159
References
0
FWCI
3.91
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Enhanced photocatalytic formation of hydroxyl radicals on fluorinated TiO2. https://app.cochat.ai/papers/10.1039/b500194c
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Mrowetz, M., & Selli, E. (2005). Enhanced photocatalytic formation of hydroxyl radicals on fluorinated TiO2. Physical Chemistry Chemical Physics. https://doi.org/10.1039/b500194c

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