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A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
Abstract
A new microporous metal-organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.
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Cited by
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationPerry IV, J. J., Perman, J. A., & Zaworotko, M. J. (2009) · Chemical Society Reviews · doi:10.1039/b807086p · Cited by 1,768
Ligand design for functional metal–organic frameworks
Almeida Paz, F. A., Klinowski, J., Vilela, S. M. F., Tomé, J. P. C., Cavaleiro, J. A. S., & Rocha, J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15055c · Cited by 855
Infinite coordination polymer nano- and microparticle structures
Spokoyny, A. M., Kim, D., Sumrein, A., & Mirkin, C. A. (2009) · Chemical Society Reviews · doi:10.1039/b807085g · Cited by 788
Recent advances in crystal engineering
Aakeröy, C. B., Champness, N. R., & Janiak, C. (2010) · CrystEngComm · doi:10.1039/b919819a · Cited by 746
Metadata
- Authors
- Cho, S.-H., Ma, B., Nguyen, S. T., Hupp, J. T., & Albrecht-Schmitt, T. E.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Issue
- 24
- Pages
- 2563-2565
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2149101244
- Cited by
- 968
- References
- 0
- FWCI
- 51.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cho, S.-H., Ma, B., Nguyen, S. T., Hupp, J. T., & Albrecht-Schmitt, T. E. (2006). A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation. Chem. Commun. https://doi.org/10.1039/b600408c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.