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Molecular oxygen and oxidation catalysis by phosphovanadomolybdates
Abstract
The history of aerobic catalytic oxidation mediated by a subclass of polyoxometalates, the phosphovanadomolybdates of the Keggin structure, [PV(x)Mo(12-x)O40](3+x)-, is described. In the earlier research it was shown that phosphovanadomolybdates catalyze oxydehydrogenation reactions through an electron-transfer oxidation of a substrate by the polyoxometalate that is then reoxidized by oxygen. These aerobic oxidations are selective and synthetically useful in various transformations, notably diene aromatization, phenol dimerization and alcohol oxidation. Oxygen transfer from the polyoxometalate to arenes and alkylarenes was also discussed as a homogeneous analog of a Mars-van Krevelen oxidation. "Second generation" catalysts include binary complexes of the polyoxometalate and a organometallic compound useful, for example, for methane oxidation and nanoparticles stabilized by polyoxometalates effective for aerobic alkene epoxidation.
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Cites
Multicopper oxidases and oxygenases
Solomon, E. I., Sundaram, U. M., & Machonkin, T. E. (1996) · Chemical Reviews · doi:10.1021/cr950046o · Cited by 3,664
Özkar, S., & Finke, R. G. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012749v · Cited by 293
Cited by
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Cavani, F., & Teles, J. H. (2009) · ChemSusChem · doi:10.1002/cssc.200900020 · Cited by 548
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure
Kimura, T., Kamata, K., & Mizuno, N. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203189 · Cited by 264
Metadata
- Authors
- Neumann, R., & Khenkin, A. M.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Issue
- 24
- Pages
- 2529
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2145880313
- Cited by
- 186
- References
- 2
- FWCI
- 6.73
- Type
- journal article
- Language
- en
- Open access
- closed
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