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Cited by 315

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Magnetothermal properties of molecule-based materials

Open access
Evangelisti, M., Luis, F., de Jongh, L. J., Affronte, M.·2006·Journal of Materials Chemistry

Abstract

We critically review recent results obtained by studying the low-temperature specific heat of some of the most popular molecule-based materials. After introducing the experimental techniques and basic theoretical framework needed for heat capacity determination and understanding, we report on the magnetothermal properties of molecular antiferromagnetic wheels. For selected molecular high-spin clusters, particular emphasis is devoted to magnetic quantum tunnelling and coherence as well as collective phenomena as probed by heat capacity experiments. We discuss also the possibilities of application of molecule-based materials for magneto-cooling at low temperatures and the limitations in other temperature ranges. Perspectives for future developments are mentioned as well.

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Metadata

Authors
Evangelisti, M., Luis, F., de Jongh, L. J., & Affronte, M.
Venue
Journal of Materials Chemistry
Published
2006
Volume
16
Issue
26
Pages
2534
ISSN
  • 0959-9428 (ISSN-L)
  • 1364-5501
OpenAlex
W2100196856
Cited by
315
References
2
FWCI
7.16
Type
journal article
Language
en
Open access
green

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