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The chemistry of functionalised N-heterocyclic carbenes
Abstract
This tutorial review presents the synthesis, chemistry and applications of functionalised N-heterocyclic carbenes NHC and their transition metal complexes. Functionalised NHC comprise those carrying a phosphino-, amino-, imino- or oxygen-containing functionality on the imidazole sidechain. Main applications have been the modification of catalysts and their immobilisation by fixation on a polymeric support using the functional group. Whereas the functionalisation of the NHC has not improved their performance in catalysis, new developments have occurred in the use of imidazole-containing biomolecules such as L-histidine or caffeine as precursors for NHC.
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Cited by
Huang, B.-H., Tsai, C.-Y., Chen, C.-T., & Ko, B.-T. (2016) · Dalton Transactions · doi:10.1039/c6dt03384a · Cited by 75
Metadata
- Authors
- Kühl, O.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Volume
- 36
- Issue
- 4
- Pages
- 592-607
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W1993082419
- Cited by
- 458
- References
- 0
- FWCI
- 1.38
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
