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Exfoliating layered double hydroxides in formamide: a method to obtain positively charged nanosheets
Abstract
Exfoliation of layered double hydroxides (LDHs) into single layers provides a new type of nanosheet with ultimate two-dimensional anisotropy and positive charge. In this Highlight article, we briefly review the latest advances in this emerging field. In comparison with the previous studies, we show that micrometer-sized and well-defined LDH nanosheets can be readily attained by synthesizing large crystals of LDH-carbonate via so-called homogeneous precipitation and subsequent exfoliation of the nitrate form in formamide. Some general aspects including the exfoliating process and characterization, a plausible delaminating mechanism, and future challenges, are presented and discussed.
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Cited by
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Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Liang, H., Meng, F., Cabán-Acevedo, M., Li, L., Forticaux, A., Xiu, L., Wang, Z., & Jin, S. (2015) · Nano Letters · doi:10.1021/nl504872s · Cited by 987
Self-citationMa, W., Ma, R., Wang, C., Liang, J., Liu, X., Zhou, K., & Sasaki, T. (2015) · ACS Nano · doi:10.1021/nn5069836 · Cited by 714
Self-citationExfoliated oxide nanosheets: new solution to nanoelectronics
Osada, M., & Sasaki, T. (2009) · Journal of Materials Chemistry · doi:10.1039/b820160a · Cited by 608
Self-citationSelf-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Metadata
- Authors
- Ma, R., Liu, Z., Li, L., Iyi, N., & Sasaki, T.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Volume
- 16
- Issue
- 39
- Pages
- 3809
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W1984439968
- Cited by
- 528
- References
- 0
- FWCI
- 7.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ma, R., Liu, Z., Li, L., Iyi, N., & Sasaki, T. (2006). Exfoliating layered double hydroxides in formamide: a method to obtain positively charged nanosheets. Journal of Materials Chemistry. https://doi.org/10.1039/b605422f
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