The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Catalytic performance of Rh/SiO2 in glycerol reaction under hydrogen
Open accessAbstract
Glycerol is a main byproduct in the biodiesel production process, and the effective utilization of glycerol can contribute to biodiesel promotion. One of the possible methods is the catalytic conversion of glycerol to valuable chemicals, and this can also agree with the concept of green chemistry in terms of the utilization of renewable resources. Catalytic performance of supported metal catalysts (metal: Rh, Ru, Pt, Pd support: active carbon, SiO2, Al2O3) was evaluated in the reaction of glycerol aqueous solution under H2. It is found that Rh/SiO2 exhibited higher activity and higher selectivity to hydrogenolysis products such as propanediols and propanols than Ru/C catalysts at low temperature (393 K). We also investigated the additive effect of ion-exchange resin (Amberlyst). Regarding the reaction route in the reaction of glycerol, it is suggested that the consecutive hydrogenolysis of propanediols to propanols on Rh/SiO2 can proceed via 1,2-propanediol, while it can proceed on Ru/C via 1,3-propanediol.
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Cites
Biorefineries: Current status, challenges, and future direction
Fernando, S., Adhikari, S., Chandrapal, C., & Murali, N. (2006) · Energy & Fuels · doi:10.1021/ef060097w · Cited by 709
Cited by
Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals
Ruppert, A. M., Weinberg, K., & Palkovits, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105125 · Cited by 836
Heterogeneous catalysis of the glycerol hydrogenolysis
Nakagawa, Y., & Tomishige, K. (2011) · Catalysis Science & Technology · doi:10.1039/c0cy00054j · Cited by 411
Self-citationTuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood
Van den Bosch, S., Schutyser, W., Koelewijn, S.-F., Renders, T., Courtin, C. M., & Sels, B. F. (2015) · Chemical Communications · doi:10.1039/c5cc04025f · Cited by 388
Huang, Z., Cui, F., Kang, H., Chen, J., Zhang, X., & Xia, C. (2008) · Chemistry of Materials · doi:10.1021/cm8006233 · Cited by 362
Metadata
- Authors
- Furikado, I., Miyazawa, T., Koso, S., Shimao, A., Kunimori, K., & Tomishige, K.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Volume
- 9
- Issue
- 6
- Pages
- 582
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2139985380
- Cited by
- 250
- References
- 1
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- green
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- Furikado, I., Miyazawa, T., Koso, S., Shimao, A., Kunimori, K., & Tomishige, K. (2007). Catalytic performance of Rh/SiO2 in glycerol reaction under hydrogen. Green Chemistry. https://doi.org/10.1039/b614253b
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