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The oxa-Michael reaction: from recent developments to applications in natural product synthesis
Abstract
In marked contrast to Michael reactions, oxa-Michael reactions have not been used as standard transformations in organic synthesis until quite recently. This was mainly due to a lack of reactivity and selectivity, although the potential products of such reactions are valuable intermediates. This tutorial review presents recent major advances in the field of oxa-Michael (sometimes called oxo-Michael or oxy-Michael) reactions and applications in the total synthesis of complex natural products.
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Cited by
Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639
The Thiol-Michael Addition Click Reaction: A Powerful and Widely Used Tool in Materials Chemistry
Nair, D. P., Podgórski, M., Chatani, S., Gong, T., Xi, W., Fenoli, C. R., & Bowman, C. N. (2014) · Chemistry of Materials · doi:10.1021/cm402180t · Cited by 1,596
Nucleophile-Initiated Thiol-Michael Reactions: Effect of Organocatalyst, Thiol, and Ene
Chan, J. W., Hoyle, C. E., Lowe, A. B., & Bowman, M. (2010) · Macromolecules · doi:10.1021/ma101069c · Cited by 383
Chan, J. W., Yu, B., Hoyle, C. E., & Lowe, A. B. (2008) · Chemical Communications · doi:10.1039/b813438c · Cited by 252
Metadata
- Authors
- Nising, C. F., & Bräse, S.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 37
- Issue
- 6
- Pages
- 1218
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2120801539
- Cited by
- 467
- References
- 0
- FWCI
- 0.91
- Type
- journal article
- Language
- en
- Open access
- closed
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