The DOI matches its Crossref record.
The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation
Abstract
This tutorial review describes the development of discrete transition metal complexes as electrocatalysts for H2 formation and oxidation. The approach involves the study of thermodynamic properties of metal hydride intermediates and the design of ligands that incorporate proton relays. The work is inspired by structural features of the H2ase enzymes and should be of interest to researchers in the areas of biomimetic chemistry as well as catalyst design and hydrogen utilization.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Gao, M.-R., Xu, Y.-F., Jiang, J., & Yu, S.-H. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35310e · Cited by 1,610
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Earth-abundant hydrogen evolution electrocatalysts
McKone, J. R., Marinescu, S. C., Brunschwig, B. S., Winkler, J. R., & Gray, H. B. (2014) · Chem. Sci. · doi:10.1039/c3sc51711j · Cited by 727
Metadata
- Authors
- Rakowski DuBois, M., & DuBois, D. L.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 38
- Issue
- 1
- Pages
- 62-72
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2119367081
- Cited by
- 619
- References
- 0
- FWCI
- 1.21
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation. https://app.cochat.ai/papers/10.1039/b801197b
- The paper
- Rakowski DuBois, M., & DuBois, D. L. (2009). The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation. Chem. Soc. Rev. https://doi.org/10.1039/b801197b
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
