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Photocatalytic hydrogen production from water using porous material [Ru2(p-BDC)2]n
Abstract
We have detected the first example of open porous metal–organic frameworks (MOFs) that functions as an activity site for the reduction of water into hydrogen molecules in the presence of Ru(bpy)32+, MV2+, and EDTA–2Na under visible light irradiation. This activity is highly efficient: the turnover number based on MOFs and the apparent quantum yield are 8.16 and 4.82%, respectively. Furthermore, this material enables the adsorption of various gases into its pores; its hydrogen uptake capacity is 1.2 wt% at 77.4 K.
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Cited by
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
Metal–organic frameworks as a platform for clean energy applications
Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Photocatalytic Metal–Organic Framework from CdS Quantum Dot Incubated Luminescent Metallohydrogel
Saha, S., Das, G., Thote, J., & Banerjee, R. (2014) · Journal of the American Chemical Society · doi:10.1021/ja509019k · Cited by 365
Metadata
- Authors
- Kataoka, Y., Sato, K., Miyazaki, Y., Masuda, K., Tanaka, H., Naito, S., & Mori, W.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 2
- Issue
- 4
- Pages
- 397
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2136957412
- Cited by
- 249
- References
- 0
- FWCI
- 1.60
- Type
- journal article
- Language
- en
- Open access
- closed
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