The DOI matches its Crossref record.
Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature
Abstract
Home-prepared (HP) rutile TiO2catalysts were prepared at room temperature by using H2O and TiCl4 in different ratios and without addition of additives. The catalysts were used for carrying out the selective photocatalytic oxidation of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde in aqueous suspension, free from any organic co-solvent. The selectivities showed by the home prepared catalysts were in the 45–74% range, up to four times higher than that of a commercial rutile TiO2 sample, the reaction rates being comparable. By using the most selective photocatalyst, the oxidation of benzyl, 4-methylbenzyl, and 4-nitrobenzyl alcohols was also carried out in order to investigate the influence of the substituent group on the oxidation rate and selectivity. The presence of an –OCH3group positively influenced the selectivity whereas a –NO2group showed to have a detrimental effect. The Hammett relationship effectively describes the influence of substituent group on the kinetic constant of partial oxidation of aromatic alcohols to aldehydes.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Yan, J., Wu, G., Guan, N., Li, L., Li, Z., & Cao, X. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50927c · Cited by 684
Zhang, N., Ciriminna, R., Pagliaro, M., & Xu, Y.-J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00056k · Cited by 406
Tanaka, A., Hashimoto, K., & Kominami, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305225s · Cited by 398
Shi, X., Zhang, Y., Liu, X., Jin, H., Lv, H., He, S., Hao, H., & Li, C. (2019) · Catalysts · doi:10.3390/catal9050426 · Cited by 23
Metadata
- Authors
- Yurdakal, S., Palmisano, G., Loddo, V., Alagöz, O., Augugliaro, V., & Palmisano, L.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 11
- Issue
- 4
- Pages
- 510
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2069718396
- Cited by
- 172
- References
- 0
- FWCI
- 7.79
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature. https://app.cochat.ai/papers/10.1039/b819862d
- The paper
- Yurdakal, S., Palmisano, G., Loddo, V., Alagöz, O., Augugliaro, V., & Palmisano, L. (2009). Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature. Green Chemistry. https://doi.org/10.1039/b819862d
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
