The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Direct conversion of inulin to 5-hydroxymethylfurfural in biorenewable ionic liquids
Abstract
In this work, we found that inulin is soluble in ionic liquids (ILs) choline chloride (ChoCl)/oxalic acid and ChoCl/citric acid, which are prepared entirely from cheap and renewable materials. On the basis of this discovery, we conducted the one pot reaction for the conversion of inulin into 5-hydroxymethylfurfural (HMF), which is a potential substitute for petroleum-based building blocks, using the two ILs as catalysts and solvents. The effects of reaction time, temperature and water added on the reaction were studied. It is demonstrated that the ILs are very efficient for the reaction at relatively lower temperature and could be reused after simple separation.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Self-citationAcid-Catalyzed Production of 5-Hydroxymethyl Furfural from d-Fructose in Subcritical Water
Salak Asghari, F., & Yoshida, H. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie051088y · Cited by 500
Cited by
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Francisco, M., van den Bruinhorst, A., & Kroon, M. C. (2012) · Green Chemistry · doi:10.1039/c2gc35660k · Cited by 814
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2011) · Chemical Reviews · doi:10.1021/cr100171a · Cited by 800
Extraction desulfurization process of fuels with ammonium-based deep eutectic solvents
Li, C., Li, D., Zou, S., Li, Z., Yin, J., Wang, A., Cui, Y., Yao, Z., & Zhao, Q. (2013) · Green Chemistry · doi:10.1039/c3gc41067f · Cited by 481
Metadata
- Authors
- Hu, S., Zhang, Z., Zhou, Y., Song, J., Fan, H., & Han, B.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 11
- Issue
- 6
- Pages
- 873
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2115595224
- Cited by
- 210
- References
- 5
- FWCI
- 8.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hu, S., Zhang, Z., Zhou, Y., Song, J., Fan, H., & Han, B. (2009). Direct conversion of inulin to 5-hydroxymethylfurfural in biorenewable ionic liquids. Green Chemistry. https://doi.org/10.1039/b822328a
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