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Selective gas adsorption in a microporous metal–organic framework constructed of CoII4 clusters
Abstract
A porous metal-organic framework, [Co(II)(4)(micro-OH(2))(4)(MTB)(2) x (H(2)O)(4)](n) x 13nDMF x 11nH(2)O (SNU-15), has been prepared; the X-ray crystal structure reveals a CaF(2)-like structure that generates 3D channels and the desolvated solid [Co(II)(4) (micro-OH(2))(4)(MTB)(2)](n) (SNU-15') exhibits selective gas sorption properties for H(2) and O(2) gases over N(2) at 77 K, with exceptionally high O(2) density, as well as for CO(2) over CH(4) at 195 and 273 K, suggesting its potential application in gas separation processes.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks
Choi, H., & Suh, M. P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200902836 · Cited by 389
Self-citationSumida, K., Horike, S., Kaye, S. S., Herm, Z. R., Queen, W. L., Brown, C. M., Grandjean, F., Long, G. J., Dailly, A., & Long, J. R. (2010) · Chemical Science · doi:10.1039/c0sc00179a · Cited by 347
Metadata
- Authors
- Cheon, Y. E., & Suh, M. P.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Issue
- 17
- Pages
- 2296
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2092768285
- Cited by
- 181
- References
- 0
- FWCI
- 14.18
- Type
- journal article
- Language
- en
- Open access
- closed
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