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Synthesis of floriated ZnFe2O4 with porous nanorod structures and its photocatalytic hydrogen production under visible light
Abstract
Floriated ZnFe2O4 with porous nanorod structures were successfully synthesized via mild hydrothermal and calcination processes by using cetyltrimethylammonium bromide (CTABr) as a template-directing reagent. The resulting ZnFe2O4 was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS) and nitrogen adsorption measurement. It was found that the floriated ZnFe2O4 nanostructures were composed of porous nanorods with an average length of 122 nm and diameter of 29 nm. The obtained ZnFe2O4 with a bandgap of ∼1.94 eV was firstly used as a visible-light-driven photocatalyst for hydrogen production, and exhibits remarkable photostability in an aqueous suspension by using CH3OH as a sacrificial reagent. Moreover, the possible photo-reaction mechanism for the hydrogen production from CH3OH aqueous solution was proposed for better understanding the photocatalytic behavior of ZnFe2O4 without Pt-loading.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
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Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Heterogeneous Fenton catalysts: A review of recent advances
Thomas, N., Dionysiou, D. D., & Pillai, S. C. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124082 · Cited by 889
Solar-to-fuels conversion over In2O3/g-C3N4 hybrid photocatalysts
Cao, S.-W., Liu, X.-F., Yuan, Y.-P., Zhang, Z.-Y., Liao, Y.-S., Fang, J., Loo, S. C. J., Sum, T. C., & Xue, C. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2013.10.029 · Cited by 458
Visible light-assisted heterogeneous Fenton with ZnFe2O4 for the degradation of Orange II in water
Cai, C., Zhang, Z., Liu, J., Shan, N., Zhang, H., & Dionysiou, D. D. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.09.056 · Cited by 431
Nanosheet-Assembled ZnFe2O4 Hollow Microspheres for High-Sensitive Acetone Sensor
Zhou, X., Li, X., Sun, H., Sun, P., Liang, X., Liu, F., Hu, X., & Lu, G. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b03537 · Cited by 285
Metadata
- Authors
- Lv, H., Ma, L., Zeng, P., Ke, D., & Peng, T.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 20
- Issue
- 18
- Pages
- 3665
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2133726832
- Cited by
- 280
- References
- 1
- FWCI
- 5.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lv, H., Ma, L., Zeng, P., Ke, D., & Peng, T. (2010). Synthesis of floriated ZnFe2O4 with porous nanorod structures and its photocatalytic hydrogen production under visible light. Journal of Materials Chemistry. https://doi.org/10.1039/b919897k
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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