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A new approach to fabricate graphene nanosheets in organic medium: combination of reduction and dispersion
Abstract
The direct dispersion of graphene nanosheets (GNS) in an organic medium, without assistance of dispersing agents, has been considered to be an insurmountable challenge. Herein we report a new approach to the fabrication of GNS by ethylenediamine (EDA) reduction in N,N-dimethylformamide (DMF). By this method, chemical reduction as well as dispersion of GNS can be carried out in one step. Characterization indicated that the bulk of oxygen-containing functional groups were removed from graphene oxide, and stable DMF colloidal suspensions containing homogeneously dispersed GNS were successfully obtained. Our findings make it possible to prepare graphene-based nanocomposites using a quick and low-cost solution processing technique.
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Cites
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Cited by
Chabot, V., Higgins, D., Yu, A., Xiao, X., Chen, Z., & Zhang, J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43385d · Cited by 1,119
Functional Composite Materials Based on Chemically Converted Graphene
Bai, H., Li, C., & Shi, G. (2011) · Advanced Materials · doi:10.1002/adma.201003753 · Cited by 1,080
Ammonia solution strengthened three-dimensional macro-porous graphene aerogel
Han, Z., Tang, Z., Li, P., Yang, G., Zheng, Q., & Yang, J. (2013) · Nanoscale · doi:10.1039/c3nr00971h · Cited by 199
Metadata
- Authors
- Che, J., Shen, L., & Xiao, Y.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 20
- Issue
- 9
- Pages
- 1722
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W1970305600
- Cited by
- 243
- References
- 2
- FWCI
- 9.88
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
