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Immobilization of molecular catalysts in supported ionic liquid phases
Abstract
In a supported ionic liquid phase (SILP) catalyst system, an ionic liquid (IL) film is immobilized on a high-surface area porous solid and a homogeneous catalyst is dissolved in this supported IL layer, thereby combining the attractive features of homogeneous catalysts with the benefits of heterogeneous catalysts. In this review reliable strategies for the immobilization of molecular catalysts in SILPs are surveyed. In the first part, general aspects concerning the application of SILP catalysts are presented, focusing on the type of catalyst, support, ionic liquid and reaction conditions. Secondly, organic reactions in which SILP technology is applied to improve the performance of homogeneous transition-metal catalysts are presented: hydroformylation, metathesis reactions, carbonylation, hydrogenation, hydroamination, coupling reactions and asymmetric reactions.
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Citations
Cites
Applications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
Cited by
Zhang, S., Zhang, J., Zhang, Y., & Deng, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00509 · Cited by 659
Recent approaches for C–C bond formation via direct dehydrative coupling strategies
Kumar, R., & Van der Eycken, E. V. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35397k · Cited by 294
Metadata
- Authors
- Van Doorslaer, C., Wahlen, J., Mertens, P., Binnemans, K., & De Vos, D.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 39
- Issue
- 36
- Pages
- 8377
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2068608257
- Cited by
- 242
- References
- 1
- FWCI
- 7.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Van Doorslaer, C., Wahlen, J., Mertens, P., Binnemans, K., & De Vos, D. (2010). Immobilization of molecular catalysts in supported ionic liquid phases. Dalton Transactions. https://doi.org/10.1039/c001285h
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