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Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco)
Abstract
The synthesis and structure of a new flexible metal-organic framework Ni(2)(2,6-ndc)(2)(dabco) (DUT-8(Ni), DUT = Dresden University of Technology, 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane) as well as its characterization by gas adsorption and (129)Xe NMR spectroscopy is described. The compound shows reversible structural transformation without loss of crystallinity upon solvent removal and physisorption of several gases. Xenon adsorption studies combined with (129)Xe NMR spectroscopy turn out to be favorable methods for the detection and characterization of the so-called "gate-pressure" effect in this novel MOF material. The linewidth and chemical shift of the (129)Xe NMR signal are shown to be very sensitive parameters for the detection of this structural transition from a narrow pore system with low porosity to a wide pore state. The transition and threshold temperature is clearly detected.
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Citations
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Gating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Metadata
- Authors
- Klein, N., Herzog, C., Sabo, M., Senkovska, I., Getzschmann, J., Paasch, S., Lohe, M. R., Brunner, E., & Kaskel, S.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 12
- Issue
- 37
- Pages
- 11778
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2045321100
- Cited by
- 162
- References
- 0
- FWCI
- 4.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco). https://app.cochat.ai/papers/10.1039/c003835k
- The paper
- Klein, N., Herzog, C., Sabo, M., Senkovska, I., Getzschmann, J., Paasch, S., Lohe, M. R., Brunner, E., & Kaskel, S. (2010). Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco). Physical Chemistry Chemical Physics. https://doi.org/10.1039/c003835k
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